Cu thin films preamble main objective of the present work is to develop a simple, low cost thin film solar cell using a very familiar semi conducting material like cadmium sulphide. Cadmium sulphide cds has been extensively studied for optoelectronic application since it has a direct band gap of 2. Later, it was shown that evaporated polycrystalline films of cadmium sulfide could also be used to prepare solar cells ref. Since cdse is an n type semiconductor, the minority carriers swept to the in. Thin films of cds have received widespread attention in the direction of other device applications. However, the particle size and properties of the cdsn products depend largely on the.
Solar cells cadmium sulfide cadmium sulfide is a semiconductor that has a very wide band gap of about 2. Pdf cadmium sulfide nanostructures for photovoltaic devices. Synthesis of cadmium sulphide nanoparticles synthesis of cadmium sulphide nanoparticles pattabi, manjunatha. Aug 01, 2008 hybrid photovoltaic pv cells based on cadmium sulphide cds single crystal and phthalocyanine pc films have been developed and their pv performance was measured. A decade later it was observed that a layer of cadmium sulfide on top could increase the conversion efficiency from about 5% to about 8%. Cadmium telluride cdte photovoltaics solarfeeds marketplace. Two different fabrication techniques were used for depositing the organic and inorganic layers of cupc and cds. Synthesis and characterization of cadmium sulfide cds.
Investigation of some materials as buffer layer in copper. Dec 18, 2017 the composition of these devices was verified by energy dispersive xray analysis edx. Cadmium sulphide incorporated reduced graphene oxide as counter electrode for dye sensitized solar cell sandhya murali, f. Since the early 1950s, cadmium telluride has been known as a good candidate for solar cells since it could be doped n and ptype and its band gap at 1.
Applications of graphene or its derivatives in solar cells and reported device performance. Low temperature photoluminescence studies on sputter deposited cadmium sulphidecadmium telluride heterojunctions and solar cells by mohit tuteja thesis submitted in partial fulfillment of the requirements for the degree of master of science in materials science and engineering in the graduate college of the. Cadmium telluride solar cell, a photovoltaic device that produces electricity from light by using a thin film of cadmium telluride cdte. P under my guidance, at the department of physics, cochin university of science and technology, and has not been included in any other thesis submitted previously for the award of any degree. It occurs in nature with two different polymorphs, cubic hawleyite and hexagonal greenockite. Currently, around 80% of solar cells is made of polycrystaline or single crystal silicon 10. The wide band gap, low absorption loss, compact crystallographic cell structure and electronic affinity makes cds is a promising optoelectronic device for making solar cell cise and inp. Solar cells cadmium sulfide solar cells cadmium sulfide.
A cell is formed of a glass substrate 10, a front contact 12 made, for example, of tin oxide, a cadmium sulphide layer 14 and a copper sulphide layer 16. Preparation and characterization of sn02, cds and pcds. Cadmium telluride solar cells photovoltaic research nrel. Cadmium sulphidecadmium selenide quantum dot solar cells. This paper deals with easy, simple, fast and low cost synthesis of cadmium sulfide nanoparticles by. This work involves characterization of cadmium zinc telluride films and solar cells prepared by close spaced sublimation.
Fabrication and characterization of spray pyrolysed. A photoelectrochemical solar cell generally considered to exemplify the promise of these devices is that employing cdse as the photoelectrode, in comhination with an alkaline aqueous s,12, sz2 redox electrolyte. It is a yellow solid and a semiconductor of electricity. Us4143235a cadmium sulfide photovoltaic cell and method. Us4287383a cadmium sulfide photovoltaic cell of improved. Synthesis and characterization of cds and cdte inks for solar. Cadmium sulfide is a chemical compound that has the formula cds. Aug 31, 2000 read synthesis of cadmium sulphide nanoparticles, solar energy materials and solar cells on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.
Pv solar cells based on cdte represent the largest segment of commercial thin. Cadmium sulfide cds is a semiconducting material utilized in a variety of applications. Indium sulphide in x s y is a prominent candidate to be an alternative buffer layer to socalled toxic cadmium sulphide cds in cis based solar cells. Tahseen amin khan qasuriaa, shahid alama, nabeel anwar qureshi. Recent improvements in efficiency and environmental stability ref. The process has been investigated on various wide bandgap semiconductor materials including cadmium sulphide, cadmium oxide and zinc selenide. The spin coated mesoporous tio 2 layers on ito glass substrates were sensitized with cadmium sulphide cadmium selenide quantum dots using different number of silar successive ionic layer adsorption and reaction cycles. Pdf cadmium sulfide nanoparticles cdsn are excellent electron acceptor for hybrid solar cell applications. Us4143235a cadmium sulfide photovoltaic cell and method of. The problem with that is that some thinfilm photovoltaic solar cells contain hazardous substances like cadmium that can pose a health risk if the solar panel is simply thrown out after. Jeya rajendran advanced materials research laboratory, department of chemistry, loyola college, chennai, tn, india. Higher efficiencies of 20% or more can be achieved by two junction solar cells in which two pn junctions are connected in series one on top of the other in a tandem structure. Tech indian institute of technology madras, 2005 a thesis submitted in partial fulfillment of the requirements for the degree of master of science in the department of mechanical, materials and aerospace engineering. Graphene oxide go, reduced graphene oxide rgo, cadmium sulphide cds and cadmium sulphide preparation and characterization of dip coated zno thin films for dyesensitized solar cell applications free download abstract thin films form a fair share in the ever growing solar cell research and also in the market.
Cadmium sulfide is the inorganic compound with the formula cds. Materials like zinc sulphidezns, zinc selenideznse and indium sulphideins were tested along with cds. A cadmium sulphide solar cell manufactured by the method of claim 6. Cadmium sulfide definition is a yellowbrown poisonous salt cds used especially in electronic parts, in photoelectric cells, and in medicine. In this study, buffer layer parameters layer thickness and buffer layer bandgap have been.
Cadmium sulfide nanoparticles cdsn are excellent electron acceptor for hybrid solar cell applications. Synthesis and characterization of cadmium sulfide nanoparticles. Pdf investigation of the properties of cadmium sulphide thin. A panel comprising a plurality of cadmium sulphide solar cells manufactured by the method of claim 8. Perovskite solar cells have numerous advantages such as high optical absorption, band gap tunability, light weight, low cost and easy solution processed. Cadmium telluride solar cell photovoltaic device britannica. However, given the possibility of polycrystalline thin films by vacuum evaporation, this semiconductor is very suitable to act as window material in many heterojunctions which invariably other material will act as absorber photons and have heterojunction cells. Enhanced performance of nanoporous titanium dioxide solar. A novel technique of synthesizing nanoparticle films on biological membrane substrates is presented. The methods that have been used successfully for the production of cadmium sulphide layers in thinfilm solar cells are described. The optical, electrical, morphological, and structural properties of low cost indium tin oxide itotio 2 cdscdsezns quantum dot qd solar cells with the inexpensive silverpolyaniline counter electrode ce are reported in this study. These are re ered to as rst generation solar cells. The physical and chemical properties of thus nano particles are found.
Cadmium sulphide cds is a iivi semiconductor which is insoluble in water, but soluble in dilute mineral acids. A cadmium sulfide photovoltaic cell of improved efficiency comprising a barrier layer and cadmium sulfidecontaining bilayer, the bilayer being formed by depositing at a first temperature an initial layer of cadmium sulfide in interfacial contact with the substrate and then depositing a subsequent layer of cadmium sulfide at a second temperature which is at least 20 c. Electrodeposition of cds thinfilms from cadmium acetate and. The investigation of the fundamental properties of cds thin films is of paramount importance in the understanding and development of modern cds cells. The united states is the leader in cadmium telluride cdte photovoltaic pv manufacturing, and nrel has been at the forefront of research and development in this area. Perovskite, cadmium sulphide, rectification ratio, saturation current, electron transport layer, solar cell.
Cadmium sulfide properties, applications and the future for cds. We have successfully fabricated cds homojunction solar cell with a. The optical properties get modified due to the confinement of charge carrier within the nanoparticles. Cds thin film solar cells have now been under development for a period of 12 years ref. Results obtained with znse and zns compare favourably well with that of cds. The composition of these devices was verified by energy dispersive xray analysis edx. Cadmium sulfide definition of cadmium sulfide by merriam.
Performance of graphenecds hybrid nanocomposite thin. Characterization of cadmium zinc telluride solar cells. Cadmium sulfide is used as pigment in paints, plastics, textiles, ceramic and glass and is also used in solar cells, smoke and radiation detectors, lightemitting diodes and photomultipliers. Characterization of cadmium zinc telluride solar cells gowri sivaraman abstract. Cadmiumsulphidecoppersulphide thinfilm solar cells ieee xplore. Cadmium sulphide solar cells are photovoltaic devices in which heterojunctions are formed between ntype substrates of cadmium sulphide and ptype topotaxial layers of copper sulphide shiozawa et al 1969, stanley 1975. Cds nanolayer with different thicknesses was grown on titanium dioxide tio 2 nanoparticles by chemical bath deposition technique with varying deposition times. Cadmium sulfide nanowire arrays for window layer applications. Cdscdte based solar cells, being one of the current market leaders for thinfilm photovoltaics pv, recorded 22. Cadmium sulfide properties, applications and the future. Cadmium sulfide is a yellow to orange colored, crystalline, inorganic compound that forms toxic fumes of cadmium oxides when heated. Cdte solar cells differ from crystalline silicon photovoltaic technologies in that they use a smaller amount of semiconductora thin filmto convert absorbed light energy into. Advancements in solar technology and the rapidlyexpanding landscape of photovoltaic arrays are raising concerns about environmental toxicity namely the use of cadmium telluride cdte in most photovoltaic pv solar cells the question of what happens when indictments of current energy sources are also levied towards alternative sources is an important one. Planar heterojunction perovskite solar cell is one of the most competitive photovoltaic technologies, while charge transport materials play a crucial role.
The photovoltaic effect in cadmium sulfide cds was discovered by reynolds in. Thin films of cadmium sulphide with thicknesses ranging from 0. The invention relates to the manufacture of cadmium sulphide solar cells. Zinc cadmium sulphide and zinc sulphide as alternative. Zinc cadmium sulphide and zinc sulphide as alternative heterojunction partners for cigs2 solar cells by bhaskar kumar b. The goal was to reduce the toxic effect of cadmium containing solar cells on the environment. Cells of singlecrystal cadmium sulfide were produced with sunlight ef ficiencies up to 5 percent. The structural, optical and electrical properties of the resulting layers are discussed and related to the properties required in a highefficiency thinfilm solar cell. Highperformance cadmium sulphidebased planar perovskite.
It exhibits intrinsic ntype of conductivity caused by sulphur vacancies due to excess cadmium atoms 1. Cdte solar cells differ from crystalline silicon photovoltaic technologies in that they use a smaller amount of semiconductora thin filmto convert absorbed. Investigation of the properties of cadmium sulphide thin. Photovoltaic cells based on cadmium sulphidephthalocyanine. Cadmium sulfide enhances solar cell efficiency sciencedirect. Sicds heterojunction solar cells, fabricated by single source evaporation of cds over silicon at low temperatures. Cadmium sulfide cds nanostructures have been found to be attractive for possible applications in semiconductor lasers, light emitting diodes, photovoltaic cells, display devices and biological. It is yellow in color and commonly used as a pigment, in solar cells and photoresists. Czt is deposited by cosublimation of cdte and znte. Cadmium telluride pv is the only thin film technology with lower costs than conventional solar cells made of crystalline silicon in multikilowatt systems. Chemical bath deposition, cadmium sulphide, band gap energy, annealing. Cadmiumsulphidecoppersulphide thinfilm solar cells. Pdf cadmium sulfide nanoparticles synthesized by microwave. We successfully demonstrated an effective electron transport material, namely chemical bath deposited cadmium sulphide cds film under low temperature, in perovskitebased solar cells.
In general, the effects of mois ture have been minimized, mainly on the assumption that process is completely re versible. Cadmium sulfide is an inorganic compound with the chemical formula cds. Photovoltaic cells based on copper phthalocyanine and cadmium sulfide heterojunction this work focuses on the solar cell based on the heterostructure formed between copper phthalocyanine cupc and cadmium sulfide cds. Ramasamy ssn research centre, ssn college of engineering, kalavakam603 110, chennai, tamilnadu, india corres. Synthesis of cadmium sulphide nanoparticles, solar energy. Cells of singlecrystal cadmium sulfide were produced with sunlight. Graphene oxide go, reduced graphene oxide rgo, cadmium sulphide cds and cadmium sulphide preparation and characterization of dip coated zno thin films for dyesensitized solar cell applications free download abstract thin films form a fair share in. Hybrid photovoltaic pv cells based on cadmium sulphide cds single crystal and phthalocyanine pc films have been developed and their pv performance was measured. Second generation solar cells comprise of thin lms of materials like amorphous silicon. Cadmium telluride cdte photovoltaics or also called cadmium telluride solar cell is a kind of photovoltaic pv technology that can produce electricity from sunlight using a thinfilm of compound cadmium telluride to absorb and convert sunlight into electricity. A cadmium sulphide solar cell manufactured by the method of claim 5. Fabrication and characterization of spray pyrolysed cadmium. Tweet share post the future of the solar power industry may be bright, but solar also has a dark side the panels being built today have an estimated lifespan of 30 to 40 years and then are largely discarded. Cadmium telluride solar cell, also called cadmium telluride photovoltaic or cadmium telluride thin film, a photovoltaic device that produces electricity from light by using a thin film of cadmium telluride cdte.
Cadmium sulfide is one of the most promising materials for solar cells and of great interest for their practical applications in up to electronics and photonics. Cadmium sulfide is used as pigment in paints, plastics, textiles, ceramic and glass and is also used in solar cells, smoke and radiation detectors, lightemitting diodes and. Five different pcs have been selected as candidates for the pv cell, pccu, pcmn, pczn, pcmg, and pcvo. A cadmium sulphide solar cell manufactured by the method of claim 7. Synthesis and characterization of cadmium sulfide cds quantum dots qds for quantum dot sensitized solar cell applications k. It occurs in nature with two different crystal structures as the rare minerals greenockite and hawleyite, but is more prevalent as an impurity substituent in the similarly structured zinc ores sphalerite and wurtzite, which are the major economic sources of cadmium. Currently thin film solar cells have efficiencies in the range of 1618%. Second generation solar cells comprise of thin lms of materials like amorphous silicon, cadmium telluride and copper indium gallium diselenide. Pv solar cells based on cdte represent the largest segment of commercial thinfilm module production worldwide. Investigation of the properties of cadmium sulphide thin films for solar cell applications fahrenbruch and bube, 1983. The application of cds nanoparticles in the detection of visible radiation, enhancing efficiency of solar cells and a number of biological applications because cadmium sulphide nanoparticles exhibit excellent physical, high stability, chemical and structural properties, availability, ease of preparation and handling.877 517 1189 241 183 1358 865 1076 822 1277 809 959 849 1149 607 962 472 1345 157 1442 740 258 1338 574 173 891 559 1085 923 1303 766 1321 115 173 1441 219 1303 1210 1391 95 142 195 631 825 221 53 135 6 1306